Silver atoms were chosen because they are electrically neutral, and thus wouldn't interact with the magnetic field in the same manner that a charged object would. However, silver atoms also possess a single electron in their valence (outermost) shell, which is necessarily charged, and since charged objects in motion produce magnetic fields: in the event that there is angular momentum intrinsic to electrons, there would have a resulting magnetic field, along the direction of the spin, which would then have to be the source of any observed interaction between the greater silver atom, and the magnetic field of the apparatus.